Because of the high tax, soap was a luxury item, and it did not come into common use. Pdf cold process synthesis and properties of soaps prepared. Soap is a substance of ancient origin, the manufacture of which according to gunstone et al,1986has evolved from primitive beginnings into a sophisticated chemical process. Dissolve 5 g of naoh into 40 ml of 5050 water 95% ethanol caution. Preparation of soap cold process method is used for the production of toilet soaps and washing laundry.
Soap making involves the hydrolysis of a triglyceride fat or oil using an alkaline solution usually lye, chemical name sodium hydroxide. This soap scum can form deposits on clothes causing them to be gray or yellow in color. Soap making has remained unchanged over the centuries. Even though most of the stearate ion is a hydrocarbon chain, it dissolves in water because of the carboxylate group. The crude soap obtained from the saponification reaction contains sodium chloride, sodium hydroxide, and glycerol. Interaction of soap and detergents with cation solutions 1. The ancient roman tradition called for mixing rain water, potash and animal tallow rendered form of beef or mutton fat. Part 5 analysis gel test if all of the water has been removed from the product, the biodiesel should gel when cooled. Make careful written observations throughout this process. When a base is used as the catalyst this process is often called saponification literally soap making. The hill was the site of an important sacrificial altar, and the rainwater mixed with the mingled ashes and animal fat around the altars base.
Conclusion the soap product do have the characteristics of a good soap. How soap is made material, manufacture, making, used. Synthesis of soap from olive oil university of idaho pdf. For centuries soaps have been made from animal fats and lye naoh, which was obtained by pouring water through wood ashes.
Preparation of soap using different types of oils and. Soap has unique properties that make it an excellent surfactant surface active compound or cleaning reagent. One is hydrophilic, and it is this end of the soap molecule that loves water. Solid soaps usually consist of sodium salts of fatty acids whereas liquid soaps usually are potassium salts of fatty acids. A catalyst for the synthesis of soap journal of chemical. To precipitate out the soap, add 150 ml of a saturated sodium chloride solution to the soap mixture while stirring vigorously. The soap was prepared using sheabutter oil sbo, palm kernel oil pko and plantain peels. If necessary, soaps may be precipitated by salting out with saturated sodium chloride. Cold process synthesis and properties of soaps prepared african. I enjoyed this lab thoroughly and thought that it was worthwhile both from an educational perspective and a handson learning opportunity to produce a useful substance. Test using red and blue litmus papers shows that soap suspension is basic in nature and not acidic in nature. Preparation of soaps by using different oil and analyze their. The soap is made by the saponification process, which reacts with the oil that contains triglycerides and lye naoh.
Obtain triglyceride cooking fatoil from your ta, and place about 6 ml of the cooking oil or 6g of cooking fat into a 120 ml erlenmeyer flask. The main objective in this study is to synthesis a various zinc fatty acids soap to have a lower melting point that possess the same functions as zinc stearate. Soap is a mixture of sodium or potassium salts of various naturally occurring fatty acids. The addition of salt caused the soap to form a solid that excluded impurities, such as the sodium hydroxide. Soap most soaps are soluble sodium or potassium salts of carboxylic acids. These fatty acids, of which there are about 20 naturally occurring. Preparation of soap using different types of oils and exploring its.
Fatty acids are carboxylic acids with a long unbranched hydrocarbon. Jeuz koz geluz joy empig nicolas leblanc invented a method of making alkali soda from salt that became one of the most important chemical processes of the nineteenth century. Years of research have led to the incredible selection of soaps that we encounter in the market today, but the basics of soap formation have not changed over the years. Preparation and properties of a soap stockton university.
In this process the triglyceride is reacted with a strong base such as sodium or potassium hydroxide to produce glycerol and fatty acid salts. Soap preparation from soxhlet extracted nigerian cotton seed oil. Pdf this study was conducted to find out how different fats and oils produce soaps of different characteristics. Traditionally, soaps were made from animal fat and lye naoh. Istory of according to roman legend, soap was discovered after a heavy rain fell on the slopes of mount sapo the name means mount soap in latin. The use of locally available raw materials in soap production was carried out. Distilled water is preferred, but not essential if desired, you can prepare solutions of your lab soap and a household soap. A soapmaking suggestion journal of chemical education. Saponification is the process of making soap from alkali and fat or oil. This mixture was stirred for about 45 minutes, then left by itself for a. Experiment preparation of soap soaps are carboxylate salts with very long hydrocarbon chains. The zinc content of zinc fatty acids soap will be analysed by using mpaes. Fatty acids are carboxylic acids with a long unbranched hydrocarbon aliphatic chains.
An emulsifier is capable of dispersing one liquid into another immiscible liquid. A plastic scrubbing sheet such as scotchbrite is coarse enough to allow rapid filtration but fine enough to hold curdy soap. Reducing the number of steps in your synthesis would in practice have the benefit of. The principle of soap works because soap is made up of molecules with two very different ends. In what ways does a typical organic chemical reaction differ from a typical inorganic reaction. This means that while oil does not naturally mix with water, soap can suspend oildirt in such a way that it can be removed. Decant as much liquid off before adding the solid soap to the buchner funnel. Describe the chemical reaction that takes place in the process of saponification. These soaps contain free alkalis and are mainly used as washing bars for laundry. Hydrolysis of a triacylglycerol into glycerol and fatty acids can be catalyzed by either strong acid or strong base. Esters, fats, and soap w14 103 soapp hydrolysis of an ester is the reverse of the synthesis of an ester. Evidence of soap making dates back to the egyptian and babylonians. Trends and characteristics a report of the center for competitive analysis may 2000 this report, prepared by the center for competitive analysis of the university of missouri outreach and extension uoe, provides an overview of the soap and other. This part also determined the comparison of properties of soap and detergent in hard solution.
However, the franrance smell is too strong and may be umpleasant to certain people. The precipitates can be seen in the soapy water and are referred to as soap scum. Pdf synthesis of exotic soaps in the chemistry laboratory. Saponification synthesis and properties of soap part i. When the top layer cooled and solidified, it was cut into cubes of yellow soap sodium stearate. Soap can be made from the base hydrolysis of a fat or an oil. Soap is made from allnatural ingredients and has been around for centuries. Salts of higher fatty acids soaps are generated during. The objective of this laboratory is to make lye soap via the saponification reaction. Continue to draw air over the soap for another 3 minutes. Soap formulation lab report pages 1 16 text version. So, this is reason why detergent and soap not emulsified with oil. All books are in clear copy here, and all files are secure so dont worry about it.
Soaps are the sodium salts or potassium salts of stearic acids or any other fatty acids. While liquids and gels for personal cleansing have become a fact of life, the traditional soap bar is fighting back, initially with translucent soaps and now with transparent products. Are they alcohols, aldehydes, ketones, acids, esters, or amines. These impurities are removed by boiling the crude soap curds in water and reprecipitating the soap with salt. Soaps, will react with metal ions in the water and can form insoluble precipitates. The ph of the soap is 6 and near to the skin ph which is 5. They are prepared by the saponification process, which is, reacting the oil. After the purification process is repeated several times, the soap may be used as an inexpensive industrial cleanser. The main difference between soap and detergent is the ingredients. Saponificationthe process of making soap procedure. Cold process synthesis and properties of soaps prepared.
Synthesis of exotic soaps in the chemistry laboratory otto phanstiel iv, eric dueno, and queenie xianghong w ang department of chemistry, university of central florida, orlando, fl 32816. The general process of hydrolyzing esters with caustic alkalis strong bases such as sodium. In this way the process omylivaniya done without boiling fats with caustic lye. Soaps and detergents are used frequently in our daily life. The synthesis and properties of soaps and detergents. Detergents are made from synthetic ingredients, although natural ingredients may be included. Vegetable oils and animal fats are fatty esters in the form of triglycerides. There is a significant difference between them where the soaps are produced from the natural products while the detergents are synthetic or manmade.
Colour, texture, lathering and cleansing power of the prepared soaps. Alternatively, the wolffkishner or mozingo reaction could be used. A soap is the sodium or potassium salt of a longchain fatty acid. In organic chemistry, transesterification and saponification are important processes in the synthesis of biodiesel and soap.
The most common commercial soap is sodium stearate, nac17h35co2. An integrated introductory organic chemistry laboratory experiment. Only a few generations ago, people routinely made soap by boiling beef tallow a triglyceride with lye impure sodium hydroxide. Synthesis of synthetic detergent with friedel crafts acylation.
It is an item of daily necessity as cleaning agent. A soap molecule consists of a long hydrocarbon chain composed of carbons and hydrogens with a carboxylic acid group on one end which is ionic bonded to a metal. This hydrolysis is called saponification, and the reaction has been known for centuries. Polymer synthesis classification polymerization reactions can be classified into two or three basic types. Within this highly competitive market place soap is presented in a multitude of forms both solid and liquid. In the simplest synthesis reactions, two elements combine to form a binary compound a compound made of two elements.
Soap and detergentcontaining products are found in many colors, fragrances, and textures. You can simplify your synthesis by reducing the carbonyl group away in one step with the clemmensen reduction, which works well for arylalkyl ketones produced by friedelcrafts acylation. Place the test tube into a beaker containing ice and tap water. This process increases the density of the aqueous solution, solidifies the soap. Soap is undoubtedly the oldest product to be produced specifically as a surfactant and in its many forms continues to play a major role today. Soap is the traditional washing compound made from oil fats and caustic alkali. In this experiment we will synthesize a soap from cotton seed oil with sodium hydroxide by a process called saponification. The ionic highly polar, charged nature of salts typically makes them water soluble. Pdf a variety of different triglyceride sources ranging from vietnamese garlic oil to a local restaurants grill sludge were saponified to generate. The soap industry in india is at the high growth rate and many new.
Soap, from a chemical standpoint, is a salt or a mixture of salts of fatty acids. Although it has a low melting point, but it still consider high and problematic to the compounding system. The objectives of this experiment are to make soap using the saponification reaction. The cleansing action of soap is due to the fact that soap. Fourcountry synthesis of the enabling environment for. Saponification synthesis of soap objectives to understand the process of saponification. Three conventional methods of soap making are generally used. Fourcountry synthesis of the enabling environment for handwashing with soap endline analysis catherine obrien and michael favin october 2012 the water and sanitation program is a multidonor partnership administered by the world bank to support poor people in obtaining affordable, safe, and sustainable access to water and sanitation services. Soap preparation from soxhlet extracted nigerian cotton seed oil warra, a. The preparation of soap few college students today can recall watching soap being made. In the isolation portion, trimyristin was extracted from nutmeg through a reflux reaction. Diethyl ether, which shared similar polarities with trimyristin, was used to preferentially extract trimyristin from the more hydrophobic less polar components of nutmeg. Soap works by breaking up the oil into smaller drops, so it can mix with the water.
Graham the purpose of this experiment was to synthesize soap and observe the ph, along with the reaction when calcium chloride and iron iii chloride are added to the soap mixture. While the air is being drawn over the soap in the funnel, wash the soap with two 20 ml volumes of ice cold deionized water. This soap was milder and suitable not just for washing clothes or pots, but also for use on skin. Nicholas leblanc soap synthesis the preparation of soap through a chemical reaction is known as saponification. Pdf che485 lab report on preparation of soap and properties. Preparation of soap by walter scharf and charles malerich natural scienceschemistry baruch college new york, ny 10010 introduction soap, from a chemical standpoint, is a salt or a mixture of salts of fatty acids. Synthesis of soap today when we need soap to wash dishes, hair, clothes, the dog or ourselves, we simply go to the store and purchase a product made especially for that purpose. The fatty acid usually contains 12 to 18 carbon atoms. Experiment 7 chem 276 fall semester 2010 page 1 of 4 synthesis of soap from olive oil introduction a soap is a salt of a fatty acid.
To comprehend the role hard water ions play in the effectiveness of soap detergent. Synthesis of soap from olive oil introduction a soap is a salt of a fatty acid. Soap makers had to pay a heavy tax on all the soap they produced. Introduction a soap is a salt of a compound known as a fatty acid. Prepare a detergent solution by dissolving about 1 g your laboratory made detergent in 60 ml 4. You can make an inexpensive yet effective mix of either. Prepare a soap solution by dissolving about 1 g of your laboratory made soap in 60 ml 4 tablespoons of warm water. Synthesis of soap hannah michael c127 section 9667 ai.
This mixture was stirred for about 45 minutes, then left by itself for a week to settle out into its consituent parts. A soap is the sodium or potassium salt of a long chain fatty acid. There are few specialty soaps like the washing soaps, castile soaps, sandal soap, specially flavored soaps, medicated soaps, toilet soaps and baby soaps. The white suspension formed is made up of soap and glycerol. Soap is prepared by carrying out a hydrolysis reaction in which an ester is treated with water using an acid or base catalyst to give a carboxylic acid and an alcohol. The process of formation of soap is called saponification. Saponification of esters fats and oils is a familiar reaction of this type. Prior knowledge expected from the student the synthesis of esters. Read online synthesis of soap from olive oil university of idaho book pdf free download link book now.
Soap is an excellent cleanser because of its ability to act as emulsifying agent. Strugstad october 1st, 2010 materials included in reading package. The hydrolysis of a fat a triacylglycerol or triglyceride with a base is called saponification, and the resulting salts of the fatty acids are called soaps. The combination of iron and sulfur to form iron ii sulfide is an example of a synthesis reaction. Saponification the properties and synthesis of soap objectives. Transfer approximately 23 ml of the biodiesel into a test tube. We will then investigate some of the properties of the prepared soap.
Introduction soap is produced by the saponification hydrolysis of a triglyceride fat or oil. Synthesis of soap from olive oil university of idaho. The alkali breaks the ester bond and releases the fatty acid salt and glycerol. All of these soaps are prepared with coconut and palm kernel oil, which have the ability saponify in the cold with stirring e strong alkali metal. When soap is prepared from the potassium salts of the acids of good grade oils and fat, it results in soft soap. The tax collector locked the lids on soap boiling pans every night to prevent illegal soap manufacture after hours. To produce a small amount of soap from vegetable oil and sodium hydroxide.
Download synthesis of soap from olive oil university of idaho book pdf free download link or read online here in pdf. For example, when the drops of soap were added, the dirt will associated inside the micelles, tiny spheres formed from soap molecules with polar hydrohilic groups on the outside and the next layer is the lipophilic so that the dirt can stay in the micelles form. The figure shows the chemical reaction that is the basis for soap synthesis. There are three types of sample in test tube a, b and c which are calcium chloride, magnesium chloride and ferum chloride. Similarly, esterification is also just as important. It dissolves in water, forming the sodium and stearate ions. Carothers, a great and tragic figure in the history of polymer science, suggested that most polymers could be classified into two broad categories, condensation or addition.